Home Chemistry Solution & Colligative Properties NTA Abhiyas Question A complex is represented as CoCl 3 . xH 2 O.…
Chemistry Solution & Colligative Properties NTA Abhiyas Question Single Correct MCQ
Published on: August 14, 2026

A complex is represented as CoCl 3 . xH 2 O. Its 0.1 m solution in aqueous medium shows T f = 0.558 K. K f for water is 1.86 kg mol -1 K and assuming 100% ionisation of the complex having coordination number 6. The formula of the complex is

A
[Co(H 2 O) 4 Cl]Cl 2
B
[Co(H 2 O) 4 Cl 2 ]Cl
C
[Co(H 2 O) 6 ]Cl 3
D
[Co(H 2 O) 5 Cl]Cl 2

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The correct answer is:
D

[Co(H 2 O) 5 Cl]Cl 2

T f = i x K f x m

0.558 = i x 1.86 x 0.1 i = 3

So, the total no of ions produce by complex per mole should be 3

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